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Exponential Law of Decay

The rate of radioactive decay
  • Radioactive decay is completely random — you can't predict which atom's nucleus will decay when.
  • But although you can't predict the decay of an individual nucleus, if you take a very large number of nuclei, their overall behaviour shows a pattern.
  • Isotopes of an element have the same number of protons, but different numbers of neutrons in their nuclei.
  • Any sample of a particular isotope has the same rate of decay — i.e. the same proportion of atomic nuclei will decay in a given time.
  • Each unstable nucleus within the isotope will also have a constant decay probability.
The Decay Constant and Activity

\(\(A=\lambda N\)\)
- where \(A\) is the activity in Becquerels
- where \(\lambda\) is the decay constant in \(s^{-1}\)
- where \(N\) is the number of unstable nuclei in the sample


Also can be written as:


\(\(A=-\frac{\Delta N}{\Delta t}\)\)


Combining these equations:
\(\(\frac{\Delta N}{\Delta t}=-\lambda N\)\)
- where \(\frac{\Delta N}{\Delta t}\) is the rate of change of unstable nuclei
- where \(\lambda\) is the decay constant in \(s^{-1}\)
- where \(N\) is the number of unstable nuclei in the sample

The Decay Equation

\(\(N=N_{0}e^{-\lambda t}\)\)
- where \(N\) is the number of unstable nuclei remaining
- where \(N_{0}\) is the original amount of unstable nuclei
- where \(\lambda\) is the decay constant
- and where \(t\) is time in seconds

If asked about molar mass...

\(\(N=nN_{A}\)\)
- \(N\) is the number of atoms in a sample
- \(n\) is the number of moles in the sample
- \(N_{A}\) is Avogadro's Constant

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